Product
(1S-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid
- CAS No.: 2259-14-5
- Purity: 99%
Manufacturer supply top purity (1S-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid 2259-14-5 with GMP standards
- Molecular Formula: C10H16 O2
- Molecular Weight: 168.236
- Melting Point: 17-21°
- Boiling Point: 246.4°Cat760mmHg
- Flash Point: 119°C
- PSA： 37.30000
- Density: 1.077g/cm3
- LogP: 2.30940
(1S-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid(Cas 2259-14-5) Usage
|
General Description |
(1S-trans)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylic acid is a chemical compound with a cyclopropane ring and carboxylic acid functionality. It is a chiral compound, with the (1S-trans) configuration indicating the stereochemistry of the molecule. The presence of the cyclopropane ring and the unsaturated side chain make it a structurally interesting compound with potential applications in organic synthesis and pharmaceutical research. The compound's unique structure may also make it useful as a starting material for the synthesis of other complex molecules. Its specific properties and potential uses could be further explored in the context of its chemical and biological activities. |
InChI:InChI=1/C10H16O2/c1-6(2)5-7-8(9(11)12)10(7,3)4/h5,7-8H,1-4H3,(H,11,12)/t7?,8-/m1/s1
2259-14-5 Relevant articles
Identification of the catalytic residues of carboxylesterase from arthrobacter globiformis by diisopropyl fluorophosphate-labeling and site-directed mutagenesis
Nishizawa, Masako,Yabusaki, Yoshiyasu,Kanaoka, Masaharu
, p. 89 - 94 (2011)
The role of amino acid residues in the e...
Enzyme catalysed kinetic resolution of racemic 2,2-dimethyl-3-(2,2- disubstituted vinyl) cyclopropane carboxylic acids anchored on polymer supports
Nanda,Bhaskar Rao,Yadav
, p. 5905 - 5908 (1999)
Kinetic resolution of trans-substituted ...
Total Syntheses of All Six Chiral Natural Pyrethrins: Accurate Determination of the Physical Properties, Their Insecticidal Activities, and Evaluation of Synthetic Methods
Ashida, Yuichiro,Kawamoto, Momoyo,Matsuo, Noritada,Moriyama, Mizuki,Tanabe, Yoo
, p. 2984 - 2999 (2020/03/24)
Chiral total syntheses of all six insect...
Lewis Acid Catalyzed Enantioselective Photochemical Rearrangements on the Singlet Potential Energy Surface
Leverenz, Malte,Merten, Christian,Dreuw, Andreas,Bach, Thorsten
, p. 20053 - 20057 (2019/12/30)
The oxadi-methane rearrangement of 2,4-c...
Cyclopropanation of Terminal Alkenes through Sequential Atom-Transfer Radical Addition/1,3-Elimination
Tappin, Nicholas D. C.,Michalska, Weronika,Rohrbach, Simon,Renaud, Philippe
supporting information, p. 14240 - 14244 (2019/08/26)
An operationally simple method to affect...
Syntheses of racemic and scalemic cis-chrysanthemic acid from β,γ-unsaturated cyclohexanol
Krief, Alain,Jeanmart, Stéphane,Gondal, Humaira Y.,Kremer, Adrian
, p. 2123 - 2167 (2013/02/23)
2,2,5,5-Tetramethylcyclohexane-1,3-dione...
2259-14-5 Process route
-
-
97-41-6,1802-02-4,7377-84-6,15543-65-4,16642-27-6,34909-55-2,41641-25-2,41641-26-3,41641-27-4
ethyl trans-(+/-)-chrysanthemate
-
-
827-90-7,2259-14-5,2935-23-1,4638-92-0,10453-89-1,15259-78-6,26771-06-2,26771-11-9,705-16-8
trans-chrysanthemic acid
| Conditions | Yield |
|---|---|
|
With
potassium hydroxide;
In
ethanol; water;
for 3h;
|
86%
|
-
-
78715-54-5
tert-amyl trans-chrysanthemate
-
-
827-90-7,2259-14-5,2935-23-1,4638-92-0,10453-89-1,15259-78-6,26771-06-2,26771-11-9,705-16-8
trans-chrysanthemic acid
| Conditions | Yield |
|---|---|
|
With
potassium hydroxide;
In
ethanol;
for 24h;
Heating;
|
73%
|
2259-14-5 Upstream products
-
827-90-7
trans-chrysanthemic acid
-
97-41-6
ethyl 2,2-dimethyl-3-(2-methylpropenyl)cyclopropanecarboxylate
-
5460-63-9
chrysanthemumic acid methyl ester
-
5460-63-9
methyl (dl)-trans-chrysanthemate
2259-14-5 Downstream products
-
26770-95-6
(1S )-trans -chrysanthemumic acid-chloride
-
94672-92-1
(1S )-2.2-dimethyl-3t -(2-methyl-propenyl)-cyclopropane-carbanilide-(1r )
-
3972-20-1
allethrin I
-
5460-63-9
methyl (dl)-trans-chrysanthemate
